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亚克力是怎样“炼成”的
Published:
2020-09-15
亚克力板是聚合的典型产品。本体聚合过程可分为制浆和聚合两个阶段。但为了得到工业生产上具有一定规格和符合一定质量指标的产品,还必须有适当的辅助环节。

为了便于操作和管理,整个丙烯酸板聚合过程分为五个部分:
1、制浆部分
在单体中加入定量引发剂、增塑剂和脱模剂后,转化率约为10的浆料经I五次溶解后制备为:
A)确定生产周期,提高生产效率。在预聚合反应中,引发剂在高温下被分解,诱导期缩短,单体活化,链长。通过搅拌,加速了热交换,在短时间内消除了更多的聚合热。为了促进单体粘度的增长,凝胶效应来得更早。降解方法可以提高单体粘度,便于操作。
B)减少聚合时的体积收缩。单体比例为0.94,成品有机玻璃比例为1.17~1.19。如果将单体直接在模具中聚合成丙烯酸片,则可以达到19和22%的体积收缩。如此大的收缩率给模具制造、浇注和聚合过程带来了困难。搅拌好后。比重一般在0.96~0.98左右,可以减少聚合时的收缩。
C)当料浆粘度增加时,可以减少浇注模后漏损。
2、机械模具部分
在两个干净干燥的硅石平板玻璃中,在四边填充有玻璃纸的胶条(或胶管),控制间隙距离,调整成品厚度,用夹具夹紧后进行填充。
3、灌溉节
通过计算和测量,将制浆段产生的浆料倒入成型段制作的模具中,间隙内气体排放,使浆料被模板覆盖并密封。
4、组装部分
将成品进料液放入水箱(或烘干室)。如果在模具中是降解料浆,应在较高的温度下诱导一段时间,然后在较低的温度下保持较长时间,直到模具中的聚合物硬化,温度升高。
如果模具是预聚料浆料,可以在低温下直接保持很长时间,直到模具内的聚合物硬化,然后增加温度和热处理:聚合结束后,温度降到40OC以下。取下模具,取出所需的聚合物,生产称为“羊毛片”。
5、成品部分
检查“羊毛片”的外观,修剪、切割、分级后入库。
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